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991.
Alan T. Herlihy Jean Sifneos Chris Bason Amy Jacobs Mary E. Kentula M. Siobhan Fennessy 《Environmental management》2009,44(2):369-377
We sampled 92 wetlands from four different basins in the United States to quantify observer repeatability in rapid wetland
condition assessment using the Delaware Rapid Assessment Protocol (DERAP). In the Inland Bays basin of Delaware, 58 wetland
sites were sampled by multiple observers with varying levels of experience (novice to expert) following a thorough training
workshop. In the Nanticoke (Delaware/Maryland), Cuyahoga (Ohio), and John Day (Oregon) basins, 34 wetlands were sampled by
two expert teams of observers with minimal protocol training. The variance in observer to observer scoring at each site was
used to calculate pooled standard deviations (SDpool), coefficients of variation, and signal-to-noise ratios for each survey. The results showed that the experience level of
the observer had little impact on the repeatability of the final rapid assessment score. Training, however, had a large impact
on observer to observer repeatability. The SDpool in the Inland Bay survey with training (2.2 points out of a 0–30 score) was about half that observed in the other three basins
where observers had minimal training (SDpool = 4.2 points). Using the results from the survey with training, we would expect that two sites assessed by different, trained
observers who obtain DERAP scores differing by more than 4 points are highly likely to differ in ecological condition, and
that sites with scores that differ by 2 or fewer points are within variability that can be attributed to observer differences. 相似文献
992.
Michael J. White Daniel E. Storm Philip Busteed Scott Stoodley Shannon J. Phillips 《Environmental management》2010,45(5):1164-1174
In the United States, many state and federally funded conservation programs are required to quantify the water quality benefits
resulting from their efforts. The objective of this research was to evaluate the impact of conservation practices subsidized
by the Oklahoma Conservation Commission on phosphorus and sediment loads to Lake Wister. Conservation practices designed to
increase vegetative cover in grazed pastures were evaluated using Landsat imagery and the Soil and Water Assessment Tool (SWAT).
Several vegetative indices were derived from Landsat imagery captured before and after the implementation of conservation
practices. Collectively, these indicators provided an estimate of the change in vegetative soil cover attributable to conservation
practices in treated fields. Field characteristics, management, and changes in vegetative cover were used in the SWAT model
to simulate sediment and phosphorus losses before and after practice implementation. Overall, these conservation practices
yielded a 1.9% improvement in vegetative cover and a predicted sediment load reduction of 3.5%. Changes in phosphorus load
ranged from a 1.0% improvement to a 3.5% increase, depending upon initial vegetative conditions. The use of fertilizers containing
phosphorus as a conservation practice in low-productivity pastures was predicted by SWAT to increase net phosphorus losses
despite any improvement in vegetative cover. This combination of vegetative cover analysis and hydrologic simulation was a
useful tool for evaluating the effects of conservation practices at the basin scale and may provide guidance for the selection
of conservation measures subsidized in future conservation programs. 相似文献
993.
994.
Mohammednoor Altarawneh Daniel Carrizo Artur Ziolkowski Eric M. Kennedy Bogdan Z. Dlugogorski John C. Mackie 《Chemosphere》2009,74(11):1435-1443
This article reports the computational and experimental results of the thermal decomposition of permethrin, a potential source of dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF). We have performed a quantum chemical analysis by applying density functional theory to obtain the decomposition pathways of permethrin and the formation mechanism of dibenzofuran. We have conducted the pyrolysis experiments in a tubular reactor and identified the pyrolysis products to demonstrate the agreement between the experimental measurements and quantum chemical calculations. The initiation of the decomposition of permethrin involves principally the aromatisation of permethrin into 3-phenoxyphenylacetic acid, 2-methylphenyl ester (J) and concomitant loss of 2HCl. This rearrangement is followed by the rupture of the O–CH2 linkage in J, with a rate constant derived from the quantum chemical results of 1 × 1015 exp(−68 kcal/mol/RT) s−1 for temperatures between 700 and 1300 K. This is confirmed by finding that the rate constant for unimolecular rearrangement of permethrin into J is 1.2 × 1012 exp(−53 kcal/mol/RT) s−1 over the same range of temperatures and exceeds the direct fission rate constant at all temperatures up to 850 ± 120 °C as well as by the experimental detection of J prior to the detection of the initial products incorporating diphenyl ether, 1-methyl-3-phenoxybenzene, 3-phenoxybenzaldehyde and 1-chloromethyl-3-phenoxybenzene. As the temperature increases, we observe a rise in secondary products formed directly or indirectly (via phenol/phenoxy) including aromatics (naphthalene), biphenyls (biphenyl, 4-methyl-1,1′-biphenyl) and dibenzofuran (DF). In particular, we discover by means of quantum chemistry a direct route from 2-phenoxyphenoxy to naphthalene. We detect no polychlorinated dibenzo-p-dioxins and dibenzofurans. Unlike the case of oxidative pyrolysis [Tame, N.W., Dlugogorski, B.Z., Kennedy, E.M., 2007b. Formation of dioxins in fires of arsenic-free treated wood: Role of organic preservatives. Environ. Sci. Technol. 41, 6425–6432] where significant yields of both PCDD and PCDF were obtained, under non-oxidative conditions the thermal decomposition of permethrin does not form appreciable amounts of PCDD or PCDF and the presence of oxygen (and/or a sizable radical pool) appears necessary for the formation of dibenzo-p-dioxin itself or PCDD/F from phenol/phenoxy. 相似文献
995.
Urbanization and its impact on groundwater: a remote sensing and GIS-based assessment approach 总被引:1,自引:0,他引:1
The perils of unplanned urbanization and increasing pressure of human activities on hydro-geomorphologic system often result
in modification of the existing recharge mechanism, which leads to many environmental consequences. In the present research,
an attempt has been made to investigate the applicability of remote sensing and geographical information system (GIS) in dealing
with spatial and temporal variability of dynamic phenomena, like urbanization and its impact on groundwater. This paper covers
primarily, quantitative and qualitative impacts of urban growth on the behavior of aquifer in Ajmer city (India). Urban growth
of the Ajmer city in last 17 years has been estimated from the satellite images. Database related to urbanization and groundwater
has been created in GIS. Groundwater recharge has been computed using a water balance approach known as Water Level Fluctuation
Methodology. Recharge estimation methodology has been implemented in GIS to introduce the spatial variability of hydro-geological
characteristics. Further, temporal and spatial variations in groundwater quality and quantity have been correlated with urban
growth using overlay analysis in GIS. The study reveals a general decline in water table and quality with urbanization. Further,
remote sensing and GIS technologies have been found useful in assessment of spatial and temporal phenomena of urbanization
and its impact on groundwater system. 相似文献
996.
Epidemiological studies suggesting the possibility of harmful effects on human (specifically children’s leukaemia) due to
long-term exposure to magnetic fields of extremely low frequency (e.g. 50/60 Hz) and relatively low values (i.e. over the
microtesla range) have stirred high activity in the topic of magnetic field mitigation. To reduce these fields, it is common
to use passive metal screens (e.g. plates made of aluminium or steel). To design them, effective and fast numerical computations
are highly desirable. In this article, a method is presented, which computes various parameters of screens in a given shielding
problem and yields magnetic field distribution and shielding factors. The method takes into consideration the 3D field distribution
and is able to solve systems with large aspect ratios (thin thickness in comparison with its other dimensions); this is a
common problem where other methods such as finite elements often experience difficulties. The presented method computes separately
the field inside and outside the screens. Afterwards, the solutions are “stitched” together along the border of the subregions.
Two practical examples are given of the developed numerical method. 相似文献
997.
Thomas G. Measham 《Environmental management》2009,43(6):1096-1107
Conventional approaches to evaluation of environmental programs have tended to limit themselves to restricted measures of
program effectiveness. This paper shows how a social learning approach can be incorporated into evaluating public environmental
programs. A social learning approach is particularly suited to complex environmental challenges which are inherently difficult
to understand, predict, and manage, thus complicating the evaluation process. The paper presents an Australian case study
of dryland salinity management where there are major knowledge barriers impeding conventional management techniques. The research
presented in this paper focused on evaluating a public demonstration program to track its impact through its design, implementation,
and monitoring phases. The paper shows that, by incorporating social learning principles and practices, program evaluation
can promote collective action, critical reflection, and increased knowledge to underpin improved environmental management. 相似文献
998.
999.
Dror Hawlena 《Behavioral ecology and sociobiology》2009,64(2):205-213
Colorful tails that become cryptic during ontogeny are found in diverse taxa. Nevertheless, the evolutionary bases for this
change remain debated. Recent work suggests that colorful tails, deflective displays, and striped patterns may represent antipredator
mechanisms used by immature lizards to compensate for being more active and hence more vulnerable to predation (increased
movement hypothesis, IMH). I challenged the generality of IMH by comparing foraging behavior and frequency of tail displays
across five Acanthodactylus lizards that vary in fundamental life history traits, before and after the tail changed color. As these species underwent
changes in tail coloration, they congruently adopted less risky behaviors and reduced the frequencies of tail displays. Contrary
to expectation, in two species, the hatchling risky behavior resulted not from increased movements but from longer stay in
exposed microhabitats. I suggest that colorful tails and deflective tail displays are synergistic antipredator mechanisms
neonates use to minimize the fitness consequences of using various risky behaviors rather than increased movement alone. 相似文献
1000.
Cornelia Meinert Emma Schymanski Eberhard Küster Ralph Kühne Gerrit Schüürmann Werner Brack 《Environmental science and pollution research international》2010,17(4):885-897